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Yammy (Resurrección), Dark Rukia, Rōjūrō "Rose" Ōtoribashi , Love Aikawa , and Hachigen Ushōda .
Certain legendary characters, such as Muramasa (from the anime-exclusive Zanpakutō Unknown Tales arc) or Allon (the massive beast summoned by the Tres Bestias), unlock automatically when your profile hits specific high-level milestones. Bleach Heat The Soul 7 Unlock All Characters
Reaching floors 10, 20, and 30 unlocks alternate outfits (such as school uniforms or casual wear). Rōjūrō "Rose" Ōtoribashi